Oxidative Organic Chemistry Reactions

Selective photocatalytic oxidation of aromatic alcohols to aldehydes was performed in water in the presence of TiO 2 rutile photocatalysts that exhibited a low degree of crystallinity. The nanostructured rutile samples, prepared ex TiCl 4 at very low temperature, ensured a selectivity toward the aldehyde 3 to 4-fold h…

• SEDAT YURDAKAL

No abstract yet.

Monodisperse CoPd nanoparticles (NPs) were synthesized and studied for catalytic formic acid (HCOOH) oxidation (FAO). The NPs were prepared by coreduction of Co(acac)(2) (acac = acetylacetonate) and PdBr(2) at 260 °C in oleylamine and trioctylphosphine, and their sizes (5-12 nm) and compositions (Co(10)Pd(90) to Co(60…

• ÖNDER METİN

Abstract The photocatalytic oxidation of 4‐methoxybenzyl alcohol to p‐anisaldehyde (PAA) was performed in water with organic‐free suspensions of home‐prepared and commercial titanium dioxide (TiO2) catalysts. The nanostructured TiO2 samples were synthesised by boiling aqueous solutions of titanium tetrachloride (TiCl4…

• SEDAT YURDAKAL

Home-prepared (HP) rutile TiO2catalysts were prepared at room temperature by using H2O and TiCl4 in different ratios and without addition of additives. The catalysts were used for carrying out the selective photocatalytic oxidation of 4-methoxybenzyl alcohol to 4-methoxybenzaldehyde in aqueous suspension, free from an…

• SEDAT YURDAKAL

Home-prepared (HP) rutile TiO2catalysts were prepared at room temperature by using H2O and TiCl4 in different ratios and without addition of additives. The catalysts were used for carrying out the selective photocatalytic oxidation of 4-methoxybenzyl alcohol to 4-methoxybenzaldehyde in aqueous suspension, free from an…

• OĞUZHAN ALAGÖZ

Photoinduced atom transfer radical polymerization of methyl methacrylate initiated by in situ generation of copper (I) complex from higher oxidation state species using neat zinc oxide and iron-doped zinc oxide nanoparticles is investigated. The polymerizations proceed in a well-controlled manner under UV light at roo…

• MEHMET ATİLLA TAŞDELEN

Photochemically mediated atom transfer radical polymerization of vinyl monomers is successfully activated by ecofriendly heterogeneous mesoporous graphitic carbon nitride (mpg‐C3N4). This method pertains to the use of mpg‐C3N4 as photoactivator for reduction of initially loaded copper(II) species, thus promoting the i…

• MEHMET ATİLLA TAŞDELEN

Photochemically mediated atom transfer radical polymerization of vinyl monomers is successfully activated by ecofriendly heterogeneous mesoporous graphitic carbon nitride (mpg‐C3N4). This method pertains to the use of mpg‐C3N4 as photoactivator for reduction of initially loaded copper(II) species, thus promoting the i…

• BARIŞ KIŞKAN

The photocatalytic oxidation of benzyl alcohol (BA) and 4-methoxybenzyl alcohol (MBA) has been performed in pure water by using commercial TiO(2) samples (Sigma-Aldrich, Merck, Degussa P25) and rutile TiO(2) prepared from TiCl(4) at low temperature. Particular attention has been devoted to the identification of the pr…

• SEDAT YURDAKAL

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• SÜLEYMAN TÜREDİ

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• MURAT TOPBAŞ