N-Heterocyclic Carbenes in Organic and Inorganic Chemistry

Direct functionalization of sp 2 C−H bonds via ortho diarylation of 2-pyridyl benzene with arylbromides was achieved using ruthenium(II) catalysts containing a RuCl 2 (NHC) unit and generated from [RuCl 2 (arene)] 2 and two types of NHC precursors, pyrimidinium and benzimidazolium salts, in the presence of Cs 2 CO 3 .…

• SERPİL DEMİR DÜŞÜNCELİ

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• DUYGU BARUT CELEPCİ

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• RÜYA SAĞLAMTAŞ

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• İLHAMİ GÜLÇİN

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• AYDIN AKTAŞ

The reaction of electron-rich carbene-precursor olefins containing two imidazolinylidene moieties [(2,4,6-Me(3)C(6)H(2)CH(2))NCH(2)CH(2)N(R)Cdbond;](2) (2a: R=CH(2)CH(2)OMe, 2 b R=CH(2)Mes), bearing at least one 2,4,6-trimethylbenzyl (R=CH(2)Mes) group on the nitrogen atom, with [RuCl(2)(arene)](2) (arene=p-cymene, he…

• SERPİL DEMİR DÜŞÜNCELİ

Postcombustion CO 2 capture and the conversion of captured CO 2 into value added chemicals are integral part of today’s energy industry mainly due to their economic and environmental benefits arising from the direct utilization of CO 2 as a sustainable source. Sterically confined N -heterocyclic carbenes (NHCs) have p…

• ONUR BÜYÜKÇAKIR

A new type of carbene precursor, 1,5,6,7,8,8a-hexahydroimidazo[1,5- a ]pyridine ( 1 ), has been prepared from 2-(aminomethyl)piperidine and N,N -dimethylformamide dimethylacetal. The reactions of three imidazolidinium salts with [Rh(acac)(COD)] and [Ir(μ-OMe)(COD)] 2 were found to afford rhodium and iridium complexes…

• HAYATİ TÜRKMEN

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• RÜYA SAĞLAMTAŞ

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• PARHAM TASLIMI

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• BEYHAN YİĞİT
• İLHAMİ GÜLÇİN
• MUHAMMET KARAMAN
• MURAT YİĞİT